Chemistry B5000
Organic Mechanisms
Text | Recommended: Advanced Organic Chemistry, Part A, by Francis | |||||||
| Carey and Richard Sundberg (4th Edition Kluwer Academic/Plenum or | |||||||
| Springer Publishers, or 5th Edition Springer, 2007). | |||||||
Other Materials | The above book is recommended and the instructor will supply any | |||||||
| additional materials as needed. It is likely that some course material will | |||||||
| be from outside the recommended book. | |||||||
Class | Mon | 6.30-8.35 PM, Room MR –1307 | ||||||
| Wed | 6.30-8.35 PM, Room MR-1307 | ||||||
Course outline | This course will cover the concepts in organic chemistry, necessary to | |||||||
| understand organic reaction mechanisms. Although some of this | |||||||
| material may be adapted from undergraduate organic chemistry largely | |||||||
| as a review, substantial additions to these basic concepts will be | |||||||
| introduced. The tentative topics of this course include: bonding in | |||||||
| carbon compounds; stereochemistry and isomerism; conformation, | |||||||
| steric effects and stereoelectronic properties; reaction rates, linear free | |||||||
| energy relationships and isotope effects; substitution, addition and | |||||||
| elimination reactions; carbanions and other nucleophiles; chemistry of | |||||||
| the carbonyl group; aromaticity and reactions of aromatic compounds; | |||||||
| cycloaddition chemistry; chemistry of free radicals and carbenes. | |||||||
Models | Darling models (available in bookstore) | |||||||
| Maruzen models: |
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| Prentice Hall Molecular Model Set for Organic Chemistry | |||||||
Exams | There will be two midterms, a quizz, and a final exam. The final exam | |||||||
Homework | will be comprehensive. |
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Homework assignments will be handed out/assigned during the | ||||||||
| semester. These are not graded assignments but students may be called | |||||||
| upon to offer solutions to these problems. | |||||||
Note | The final exam will be conducted during finals week or by arrangement | |||||||
| with the class. |
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No makeup exams/quizz will be given and no exam/quizz scores will be dropped for computing the final grade.
Grades Points for each aspect of the course as well as the grading scheme are as
follows.
Exam 1: 100 points
Exam 2: 100 points
Quizz: 50 points
Comprehensive Final Exam: 100 points
Total: 350 points
Grades will be assigned as follows.
Overall > 85% = A, > 75% = B, > 65% = C, > 55% = D, lower than 55% = F.
Course objectives:
This course will cover the concepts in organic chemistry, necessary to understand organic reaction mechanisms. Although some of this material may be adapted from undergraduate organic chemistry largely as a review, substantial additions to these basic concepts will be introduced.
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| Outcome |
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1. | Learn the fundamental principles, such as: |
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| Éù Bonding in organic compounds |
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| Éù Stereochemistry and isomerism in organic molecules: |
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| determination and assignment of chirality, steric, electronic, |
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| and conformational properties of organic molecules, |
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| stereoselectivity of reactions |
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| Éù Fundamental principles of reaction kinetics, linear free energy |
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| relationships, isotope effects |
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| Éù | Nucleophilic substitution |
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| Éù Addition and elimination reactions |
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| Éù Carbanions and other carbon nucleophiles |
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| Éù Aromaticity and reactions of aromatic systems |
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| Éù | Concerted pericyclic reactions |
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| Éù Free radicals and carbenes |
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2. | Analyze and interpret data as related to the concepts described above. |
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3. | Work as part of a problem-solving team or independently as |
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4. | Learn to access and utilize chemical information technology. |
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Relationship of course to program outcomes:
The outcomes of this course contribute to the following departmental educational outcomes:
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| Departmental Outcomes |
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a. | Demonstrate an understanding of the fundamental principles of |
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| chemistry, including atomic and molecular structure, quantum |
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| chemistry, chemical bonding, stoichiometry, kinetics and mechanism, |
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| equilibrium, thermochemistry and thermodynamics, molecular |
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| structure and function, electrochemistry, and the periodic chemical |
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| properties of the elements. |
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b. | Apply the fundamental principles of chemistry to life sciences, the |
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| environment, materials, engineering, and emerging technological |
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| fields of chemistry, as well as to everyday situations. |
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c. | Conduct experiments and learn fundamental laboratory skills. |
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d. | Analyze and interpret data. |
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e. | Apply mathematical concepts to chemical problems. |
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f. | Work as part of a problem-solving team. |
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| Convey facts, theories and results about chemistry in written form. |
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h. | Use oral presentation to convey facts, theories and results about |
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| chemistry. |
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i. | Access and utilize chemical information technology. |
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j. | Design and execute scientific research. |
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k. | Apply ethical responsibilities and professional conduct. |
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Assessment tools:
- Homework problems will be assigned from the end of chapter problems. References for these will be provided and can be also found at the end of the book.
- There will be additional homework problems handed out by the instructor.
- There will be two mid term exams, one quizz, and one comprehensive final exam.
- Course feedback survey (End of course survey)
Statement on Academic Integrity:
The CCNY policy on academic integrity will be followed in this course. The document can be
found through the CCNY website by clicking on Current Students → Academic Services → Policy on Academic Integrity. All students must read the details regarding plagiarism and cheating in order to be familiar with the rules of the college. Cases where academic integrity is compromised will be prosecuted according to these rules. In addition, the Policy on Academic Integrity can be found in the Graduate Bulletin 2015-2016 in Appendix B.3 on page 187.
Accommodations for Students with Disabilities:
Qualified students with disabilities will be provided reasonable academic accommodations if determined eligible by the AccessAbility Center (AAC). Prior to granting disability accommodations in this course, the instructor must receive written verification of a student’s eligibility from the AAC, which is located in NAC 1/218. It is the student’s responsibility to initiate contact with the AAC and to follow the established procedures for having the accommodation notice sent to the instructor.
Last Updated: 06/14/2023 10:53